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Decelerating Delat S
September 24, 2008, 6:28 pm

Hitting Three Birds with One Stone, er, piece of charcoal!

Recently, my interest in a particular technology has been sparked. The process (like many things that are ecologically-sound and sensible) uses technologies which have existed for well over a century and are readily available and cheap - no fancy-shmancy new stuff necessary. A new way of thinking is all that is needed.

The center of this idea is the addition of carbon (in the form of charcoal) to the soil. This has been shown to have remarkable effects on fertility and the ability of the soil to hold moisture, nutrients, and support plant life. See Activated Carbon? The resulting soil is known as a "terra preta" and has been produced by people of the Amazon jungles many centuries ago through a process referred to as "slash and smolder" agriculture, where the smoldering biomass produced mainly charcoal which was then tilled into the soil. This is in opposition to "slash and burn", where the carbon is put into the atmosphere through complete combustion.

The charcoal used in such a manner is often referred to as "Biochar"

In addition to improving soil fertility, the carbon is more or less (on human time scales) permanently stored out of the atmosphere (where it would otherwise act to affect the global climate).

A full article on the subject can be found at Energy Bulletin . It is quite interesting, at least to me. I don't have problems with the "MEGO" ("my eyes glaze over" ) effect that is mentioned.

So, there are three critical things that this has the possibility of doing:

Removing CO2 From The Air (rather than simply preventing the addition of new CO2, which is what coal-based CO2 sequestration will do). I'm sure we are all aware of the climate change/global warming situation. What we all think of it, actually know about it, or say about it before actually knowing about it is a different story.

This correlates with what NASA climatologist James Hansen recommended - coupling carbon sequestration with biomass fuel rather than with fossil fuels in order to produce a net reduction in atmospheric CO2 concentrations. Instead of simply bringing fossil carbon to the surface, taking the energy, and sending it back underground, we would be taking carbon from the atmosphere, taking its energy (put there through photosynthesis) and then sending that carbon underground.

Produces electrical and/or thermal energy. We all had better be aware of the world's energy situation. We all seem to demand limitless amounts of cheap energy, though few people really know how it all works or what it takes to make that possible. A by-product of charcoal making is the volatile component of the biomass which can be used for energy production.

Naturally and safely enriches the soil for agriculture. We all had better be (though I know we're not) aware of the condition of the world's food producing soils and how industrial agriculture really works (by applying petroleum-derived chemicals to a dead soil "sponge" to grow food.)

Now, there obviously must be some engineering that goes into this if all three outcomes are to be accomplished in a clean and safe manner. All bickering over money and politics aside, I've described below a possible "Biochar Cogeneration Facility" for the production of energy and charcoal as a soil amendment as well as the possibility of producing feedstock for chemical manufacture. Versions of this are also discussed in that article linked above (On Energy Bulletin).

Wood, Husk, Shells, Straw and other biomass materials are shredded and homogenized. Unlike highly criticized corn alcohol, the ENTIRE biomass is utilized - not just a little sac of starch inside a kernel. Forestry and agriculture wastes would work quite well. Even municipal solid waste (paper, cardboard) could be used, but these have the possibility of being contaminated with heavy metals.

The resulting biomass is then dried, using waste heat from the generator engine block and/or exhaust and/or possibly solar energy.

The dry, homogenized biomass is fed into a kiln, heated to above 1000 K and kept under reducing conditions (very little air is allowed). In the kiln, the volatile components of the biomass are converted into flammable gases (methane, hydrogen, various other organic compounds) while the fixed carbon remains in its original state. The flammable gases can be passed through a bed of hot charcoal and converted to hydrogen and carbon monoxide. Steam may be added to facilitate the production of hydrogen.

The process could be tweaked to optimize either energy production or charcoal production/sequestration. Leaving more carbon in the reactor and producing the maximum level of charcoal would result in less energy production, but more carbon going to the soil and less to the atmosphere. Charcoal could also be gasified and used for energy production. Charcoal produced by the plant could be used as a form of energy storage, gasifying some of it during times of high energy demand.

The H2/CO mixture (called "syngas" ) is siphoned off and is used either directly for energy production or is used in further chemical synthesis. With H2 and CO, virtually every organic compound currently produced by humans in chemical facilities can be synthesized. It can also be converted to liquid fuels capable of being used in diesel engines (through Fischer-Tropsch synthesis).

The hydrogen in the gas stream may be used in the Haber-Bosch synthesis process (ammonia making), and the resulting ammonia used on the charcoal to add nitrogenous value as well. Adding the Haber process, though, would require a larger-scale operation rather than a village- or town-scale operation.

The carbon (charcoal, or biochar) left in the kiln after gasification is collected and used as a soil amendment, with the capability of sequestering large amounts of carbon dioxide in the soil for long periods of time while increasing the fertility, moisture, and nutrient holding ability of the soil. The nutrients (potassium, phosphorus) that were in the biomass before gasification are returned to the soil.

Adding charcoal to the soil produces the "terra preta" previously described. Sequestering carbon in the soil using the terra preta method is probably more technically feasible than using proposed "geosequestration" systems which store the CO2 from coal-fired power stations in a compressed state deep underground in rock strata. It is also much simpler to build the plant (a very good possibility for the developing world), and the use of biomass as fuel instead of coal means that CO2 will be actively removed from the atmosphere while producing energy and enriching the quality of soils. Coal-Fired systems produce energy, but do not remove CO2 from the air or enrich the soil.

Facilities for combustion of the syngas for energy production would consist of a diesel engine, gas turbine, and/or steam-based Rankine cycle turbine. These engines would drive a generator for electricity production, and the waste heat they produce would be collected for use as well. Part of this waste heat may be used to operate the plant itself (drying the biomass).

The waste heat may be used to heat adjacent greenhouses, while the flue gases from the syngas combustion, rich in humidity and carbon dioxide, may be funneled into the greenhouses to encourage plant growth.

This all seems to be much easier, cheaper, and more effective than coal-based geosequestration, and with available technology. There are not too many things we do which act to reverse ecological damage; most things tend to simply halt or slow further damage. This actually REVERSES damage.

Comments

Posted by  
on September 24, 2008, 11:21 pm
Carbon to the Soil is the only ubiquitous and economic place to put it.

Total CO2 Equivalence:
Once a commercial bagged soil amendment product, every suburban household can do it,
The label can tell them of their contribution, a 40# bag = 150# CO2 = 160 bags / year to cover my personal CO2 emissions. ( 20,000 #/yr , 1/2 Average )
http://www.epa.gov/climatechange/emissions/ind_calculator.html

But that is just the Carbon!
I have yet to find a total CO2 equivalent number taking consideration against some average field N2O & CH4 emissions. The New Zealand work shows 10X reductions.

This ACS study implicates soil structure as main connection to N2O soil emissions;
http://a-c-s.confex.com/crops/2008am/webprogram/Paper41955.html


biochar papers at the ACS Huston meeting see Ron Larson's post http://tech.groups.yahoo.com/group/biochar/message/1852



Biochar Studies at ACS Huston meeting;

578-I: http://a-c-s.confex.com/crops/2008am/webprogram/Session4231.html

579-II http://a-c-s.confex.com/crops/2008am/webprogram/Session4496.html

665 - III. http://a-c-s.confex.com/crops/2008am/webprogram/Session4497.html

666-IV http://a-c-s.confex.com/crops/2008am/webprogram/Session4498.html

Most all this work corroborates char soil dynamics we have seen so far . The soil GHG emissions work showing increased CO2 , also speculates that this CO2 has to get through the hungry plants above before becoming a GHG.
The SOM, MYC& Microbes, N2O (soil structure), CH4 , nutrient holding , Nitrogen shock, humic compound conditioning, absorbing of herbicides all pretty much what we expected to hear.



The Terra Preta Prayer

Our Carbon who art in heaven,
Hallowed be thy name
By kingdom come, thy will be done, IN the Earth to make it Heaven.
It will give us each day our daily bread and forgive us our atmospheric trespasses
As we forgive those who trespass against the Kyoto protocols
And lead us not into fossil fuel temptation, but diliver us from it's evil
low as we walk through the valley of the shadow of Global Warming,
I will feel no evil, your Bio-fuels and fertile microbes will comfort me,
For thine is the fungal kingdom,
and the microbe power,
and the Sequestration Glory,
For ever and ever (well at least 2000 years)
AMEN


Cheers,
Erich

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